Michael Grätzel偶尔也跨界做量子点电池，五月他们发表了一篇Advanced Materials文章5，他们通过加入硫氰酸胍进行配体交换，并用温和的热退火处理，结果表明， CsPbI3量子点的电荷迁移率和载流子扩散长度显著提高，量子点电池效率达到15.21%，是当时钙钛矿量子点电池效率最高值。
7one除了铅钙钛矿，Grätzel也开始做锡钙钛矿太阳能电池。他们在FASnI3体系中加入大体积二价有机阳离子：4-(氨甲基)-哌啶(4AMP)，这可以形成一种稳定的D-J混合结构，从而提高稳定性和光电转化效率。最终他们实现了10.9%的效率，并且连续光照500小时运行良好，文章发表在ACS Energy Letters上7。8one
1. M. V. Khenkin et al., Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures. Nature Energy 5, 35-49 (2020).
2. F. Bella et al., A water-based and metal-free dye solar cell exceeding 7% efficiency using a cationic poly(3,4-ethylenedioxythiophene) derivative. Chem Sci 11, 1485-1493 (2020).3. N. Yaghoobi Nia et al., Solution-based heteroepitaxial growth of stable mixed cation/anion hybrid perovskite thin film under ambient condition via a scalable crystal engineering approach. Nano Energy 69, (2020).4. X. Gong et al., Black phosphorus quantum dots in inorganic perovskite thin films for efficient photovoltaic application. 6, eaay5661 (2020).5. X. Ling et al., Guanidinium-Assisted Surface Matrix Engineering for Highly Efficient Perovskite Quantum Dot Photovoltaics. Adv Mater 32, e2001906 (2020).6. Y. Liu et al., Stabilization of Highly Efficient and Stable Phase-Pure FAPbI3 Perovskite Solar Cells by Molecularly Tailored 2D-Overlayers. Angew Chem Int Ed Engl 59, 15688-15694 (2020).7. M. Chen et al., High-Performance Lead-Free Solar Cells Based on Tin-Halide Perovskite Thin Films Functionalized by a Divalent Organic Cation. Acs Energy Lett, 2223-2230 (2020).8. S. Akin et al., Cyclopentadithiophene-Based Hole-Transporting Material for Highly Stable Perovskite Solar Cells with Stabilized Efficiencies Approaching 21%. ACS Applied Energy Materials 3, 7456-7463 (2020).9. F. Sadegh et al., Highly efficient, stable and hysteresis‒less planar perovskite solar cell based on chemical bath treated Zn2SnO4 electron transport layer. Nano Energy 75, (2020).10. H. Lu et al., Vapor-assisted deposition of highly efficient, stable black-phase FAPbI3 perovskite solar cells. Science 370, (2020).11. T. S. Su et al., Crown Ether Modulation Enables over 23% Efficient Formamidinium-Based Perovskite Solar Cells. J Am Chem Soc 142, 19980-19991 (2020).12. H. Zhu et al., Low-Cost Dopant Additive-Free Hole-Transporting Material for a Robust Perovskite Solar Cell with Efficiency Exceeding 21%. Acs Energy Lett, 208-215 (2020).
